Product ID:TRI-ACT 2813 INHIBITOR
MSDS Date:11/23/1993
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CKTWY

Emergency Phone: 800-462-5378

Info Phone: (312) 981-9500

Preparer: RICKY A. STACKHOUSE, PHD.

Cage: 89524

Telephone: (630) 305-1000

Cage: 89524

CYCLOHEXYLAMINE

CAS: 108-91-8

RTECS: GX0700000

DIETHYLAMINOETHANOL

CAS: 100-37-8

RTECS: KK5075000

MORPHOLINE

CAS: 110-91-8

RTECS: QD6475000

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:PRIMARY ROUTES OF EXPOSURE: EYES,
SKIN, INHALATION. EYES: CORROSIVE TO THE EYES WITH POSSIBLE
PERMANENT DAMAGE DEPENDING ON LENGTH OF EXPOSURE AND ON THE FIRST
AID GIVEN. SKIN: CORROSIVE TO THE SKIN, POSSIBLY RESULTING IN
THIRD DEGREE BURNSDEPENDING ON THE LENGTH OF EXPOSURE AND THE FIRST
AID ACTION GIVEN. CAN CAUSE ALLERGIC CONTACT DERMATITIS IN
SUSCEPTIBLE INDIVIDUALS. INGESTION: CAN CAUSE KIDNE Y DAMAGE. CAN
BE HARMFUL. INHALATION: CAN BE CORROSIVE TO THE MUCOUS MEMBRANES
AND THE LUNGS. CAN CAUSE AN ALLERGIC REACTION IN SUSCEPTIBLE
INDIVIDUALS.
Effects of Overexposure:A REVIEW OF AVAILABLE DATA DOES NOT IDENTIFY
ANY SYMPTOMS FROM EXPOSURE NOT PREVIOUSLY MENTIONED.
Medical Cond Aggravated by Exposure:A REVIEW OF AVAILABLE DATA DOES NOT
IDENTIFY ANY WORSENING OF EXISTING CONDITIONS.

First Aid:EYES: IMMED FLUSH FOR AT LEAST 15 MIN WHILE HOLDING EYELIDS
OPEN. CALL PHYSICIAN AT ONCE. SKIN: IMMED FLUSH WITH WATER FOR AT
LEAST 15 MIN. FOR LARGE SPLASH, FLOOD BODY UNDER SHOWER. CALL PHYS
AT ONCE . INGESTION: DO NOT INDUCE VOMITING. GIVE WATER. CALL PHYS
AT ONCE. INHALATION: REMOVE TO FRESH AIR. TREAT SYMPTOMS. CALL PHYS
AT ONCE. IF BREATHING STOPPED, GIVE CPR. ADMINSITER OXYGEN. CALL
PHYS AT ONCE. NOTE TO PHYSICIAN: BASED ON INDIVIDUAL REACTIONS OF
PATIENT, PHYSICIAN'S JUDGEMENT SHOULD BE USED TO CONTROL
SYMPTOMS/CLINICAL CONDITION. CAUTION: IF UNCONSCIOUS, HAVING (OTHER
INFO)

Flash Point Method:PMCC
Flash Point:=55.C, 131.F
ASTM D-93
Extinguishing Media:BASED ON THE NFPA GUIDE, USE DRY CHEMICAL, FOAM,
CARBON DIOXIDE OR OTHER EXTINGUISHING AGENT SUITABLE FOR CLASS B
FIRES. USE WATER TO COOL CONTAINERS (UNUSUAL FIRE & EXPLOS HAZARDS)
Fire Fighting Procedures:USE NIOSH-APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:MAY EVOLVE NOX UNDER FIRE CONDITIONS.
EXTINGUISHING MEDIA (CONT): EXPOSED TO FIRE. FOR LARGE FIRES, USE
WATER SPRAY OR FOG, THOROUGHLY DRENCHING THE BURNING MATERIAL.

Spill Release Procedures:TRANSPORTATION ACCIDENTS, CALL (24 HRS) (800)
462-5378. SMALL LIQUID SPILLS: CONTAIN W/ABSORB MATL SUCH AS CLAY,
SOIL OR COMMERCIALLY AVAIL ABSORBENT. SHOVEL RECLAIMED LIQUID &
ABSORBENT INTO RECOVERY OR SALVAGE DRUMS FOR DISPOSAL (CERCLA; SEC
14). LARGE LIQUID SPILLS: DIKE TO PREVENT FURTHER MOVEMENT &
RECLAIM INTO RECOVERY OR SALVAGE DRUMS OR TANK TRUCK FOR (OTHER
PRECAUTIONS)

Handling and Storage Precautions:N/P. WASTE DISPOSAL (CONT):
DISPOSAL TO A LICENSED INDUSTRIAL WASTE LANDFILL (HAZARDOUS WASTE
TREATMENT, STORAGE AND DISPOSAL FACILITY). A HAZARDOUS LIQUID WASTE
CAN ALSO BE INCINERATED IN ACCORDAN CE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
Other Precautions:SPILL RELEASE PROCEDURES (CONT): DISPOSAL (CERCLA;
SEC 14). FOR LARGE INDOOR SPILLS: EVACUATE EMPLOYEES AND VENTILATE
AREA. THOSE RESPONSIBLE FOR CONTROL AND RECOVERY SHOULD WEAR THE
PROTECTIVE EQUIPM ENT SPECIFIED UNDER CONTROL MEASURES.

Respiratory Protection:IF POSSIBLE TO GENERATE SIGNIFICANT LEVELS OF
VAPORS OR MISTS, A NIOSH APPROVED OR EQUIVALENT RESPIRATOR IS
RECOMMENDED. FOR LARGE SPILLS, ENTRY INTO LARGE TANKS, VESSELS OR
ENCLOSED SMALL SPACES WITH INADEQUATE VENTILATION, A
PRESSURE-DEMAND, SELF-CONTAINED BREATHING APPARATUS IS RECOMMENDED.
Ventilation:GENERAL VENTILATION IS RECOMMENDED. LOCAL EXHAUST
VENTILATION IS RECOMMENDED WHERE VAPORS, MISTS OR AEROSOLS MAY BE
RELEASED.
Protective Gloves:IMPERMEABLE GLOVES (I.E: NEOPRENE, NITRILE, PVC,
NATURAL RUBBER, VITON & BUTYL)
Eye Protection:FACE SHIELD WITH CHEMICAL SPLASH GOGGLES (ANSI APPROVED
- ).
Other Protective Equipment:IMPERMEABLE GLOVES, BOOTS, APRON, FACESHIELD
WITH CHEMICAL SPLASH GOGGLES. EXAMPLES OF IMPERMEABLE GLOVES
AVAILABLE ON THE MARKET ARE NEOPRENE, NITRILE, PVC, NATURAL RUBBER,
VITON AND (WORK PRACTICES)
Work Hygienic Practices:OTHER EQUIP (CONT): BUTYL. (COMPATIBILITY
STUDIES HAVE NOT BEEN PERFORMED). A FULL SLICKER SUIT IS
RECOMMENDED IF GROSS EXPOSURE IS POSSIBLE. THE AVAILABILITY OF AN
EYE (SUPPLEMENTAL SAFETY & HEALTH)
Supplemental Safety and Health
WORK PRACTICES (CONT): WASH FOUNTAIN AND SAFETY SHOWER IS RECOMMENDED.
IF CLOTHING IS CONTAMINATED, REMOVE CLOTHING AND THOROUGHLY WASH
THE AFFECTED AREA. LAUNDER COMTAMINATED CLOTHING BEFORE REUSE.

Melt/Freeze Pt:=-2.6C, 27.F
M.P/F.P Text:ASTM D-1177
Vapor Pres:N/P.DENSITY:8.1-8.2LB/GAL
Spec Gravity:0.98-0.99 @ 77F
pH:12.0-13.0(NEAT)
Viscosity:5 CPS @ 77F, ASTM D-2983
Solubility in Water:COMPLETELY
Appearance and Odor:CLEAR COLORLESS TO PALE YELLOW LIQUID; NO ODOR
SPECIFIED BY MANUFACTURER.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS (E.G.CHLORINE, PEROXIDES, CHROMATES, NITRIC ACID,
PERCHLORATES, CONC OXYGEN, PERMANGANATES) WHICH CAN GEN HEAT,
FIRES, EXPLOS & RELEASE OF TOXIC FUMES. CONT OF VAPORS W/SO2 VAPORS
WHICH MAY REACT TO FORM VI
Stability Condition to Avoid:INCOMPATIBILITY: N-NITROSAMINES-MANY ARE
CANCER-CAUSING AGENTS TO LAB ANIMALS, MAY BE FORMED WHEN CERTAIN
AMINES ARE MIXED W/NITROUS ACID, ORGANIC/INORGANIC (COND TO AVOID
POLYMER)
Hazardous Decomposition Products:THERMAL: IN EVENT OF COMBUSTION, CO,
CO2, NOX MAY BE FORMED. DO NOT BREATHE SMOKE OR FUMES. WEAR
SUITABLE PROTECTIVE EQUIPMENT.

Waste Disposal Methods:IF THIS PRODUCT BECOMES A WASTE, IT MEETS THE
CRITERIA OF A HAZARDOUS WASTE AS DEFINED UNDER THE RESOURCES
CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261. HAZ WASTE D001
AND D002. AS A HAZARDOUS LI QUID WASTE, IT MUST BE SOLIDIFIED WITH
STABILIZING AGENTS (SUCH AS SAND, FLY ASH, CEMENT) SO THAT NO FREE
LIQUID REMAINS BEFORE (HANDLING/STORAGE)

Toxicological Information:ACUTE TOXICITY STUDIES: NOT CONDUCTED ON
PROD, BUT HAVE BEEN ON SIMILAR PROD, ALONG W/HAZ INGREDS FOR THIS
PROD. RESULTS: ACUTE ORAL TOX (ALBINO RATS): SIMILAR PRODUCT
LD50=779MG/KG. 95% CONFIDENCE LI MIT=497 MG/KG-1420 MG/KG. ACUTE
DERMAL TOXICITY (ALBINO RABBITS): SIM PRODUCT: LD50=2055 MG/KG. 95%
CONF LIMIT=1346 MG/KG-3136 MG/KG. ACUTE INHAL TOX (ALBINO RATS):
SIM PRODUCT LC50= >12000 PPM (8 HR VAPOR EXP). PRIMARY SKIN IRRIT
TEST (ALBINO RABBITS): SKIN IRRIT INDEX DRAIZE RATING: SIM PRODUCT
8.0/8.0 EXTRMLY IRRIT (CORR). PRIMARY EYE IRRIT TEST (ALBINO
RABBITS): EYE IRRIT INDEX DRAIZE RATING: SIM PRODUCT 110.0/110.0
(TRANSPORT)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:AQUATIC STUDIES: 96 HOUR STATIC ACUTE LC50-RAINBOW TROUT=130
MG/L. 96 HR NO OBSERVED EFFECT CONC 32 MG/L IS BASED ON NO
MORTALITY OR ABNORMAL EFFECTS. TOXICITY RATING: SLIGHTLY TOXIC. 96
HOUR STATIC A CUTE LC50 TO FATHEAD MINNOW=75 MG/L. 96 HR NO
OBSERVED EFFECT CONC IS 5.6 MG/L BASED ON NO MORTALITY OR ABNORMAL
EFFECTS. TOXICITY RATING: MODERATELY TOXIC. 48 HR STATIC ACUTE
LC50-DAPHNIA MAGNA=190 M G/L. 48 HR NO OBSERVED EFFECT CONC IS 100
MG/L BASED ON NO MORTALITY OR ABNORMAL EFFECTS. TOXICITY RATING:
SLIGHTLY TOXIC. 96 HR STATIC ACUTE LC50 TO SHEEPSHEAD MINNOW=454
MG/L. 96 HR NO OBSERVED EFFE CT CONC IS 250 MG/L BASED (TRANSPORT)

Transport Information:PROPER SHIPPING NAME/HAZARD CODE-ALKYLAMINES,
N.O.S. (DEPENDENT UPON MODE, PACKAGE) 8 (3), UN 2734, PGII.
CONTAINS: CYCLOHEXYLAMINE, DIETHYLAMINOETHANOL, MORPHOLINE.
ECOLOGICAL INFO (CONT): ON NO MO RTALITY OR ABNORMAL EFFECTS.
TOXICITY RATING: SLIGHTLY TOXIC. 96 HR STATIC ACUTE LC50 TO MYSID
SHRIMP=131 MG/L 96 HR NO OBSERVED EFFECT CONC IS 40 MG/L BASED ON
NO MORTALITY OR ABNORMAL EFFECTS. TOXIC ITY RATING: SLIGHTLY TOXIC.
IF RELEASED INTO ENVIRONMENT, SEE CERCLA, SECTION 14. TOXICOLOGY
INFO (CONT): EXTREMELY IRRIT (CORR). SKIN SENSITIZATION:
CYCLOHEXYLAMINE CAN CAUSE SENSITIZATION (CONTACT NEHC FOR
ADDITIONAL INFORMATION)

SARA Title III Information:CERCLA/SUPERFUND, 40 CFR 117, 302:
NOTIFICATION OF SPILLS OF THIS PROD IS NOT REQ'D. SARA/SUPERFUND
AMENDMENTS & REAUTHORIZATION ACT OF 1986 (TITLE III)-SECTIONS 302,
311, 312 & 313: SEC 302-EXTREMELY HAZ SUBSTS (40 CFR 355): PROD
CONTAINSCYCLOHEXYLAMINE, LISTED IN APPENDIX A & B AS EXTRMLY HAZ
SUBST. THRESHOLD PLANNING QUANT FOR SUBST-10,000 LBS. RELEASE OF 4
LBS OF PROD WILL REQ A NOTIFICATION T O STATE EMER RESP COMMISSION.
MAY BE REQ'D TO NOTIFY NAT'L RESP CNTR. SEC 311 & 312-MSDS RQMTS
(40 CFR 370): HAZ EVAL HAS FOUND PROD TO BE HAZ. (CONTACT NEHC FOR
ADDITIONAL INFORMATION).
Federal Regulatory Information:OSHA'S HAZ COMMUNICATION RULE, 29 CFR
1910.1200: BASED ON HAZ EVALUATION, FOLLOWING INGREDIENT(S) IN
PRODUCT ARE HAZ & REASON(S) ARE SHOWN BELOW. CYCLOHEXYLAMINE-CORR
TO EYES/SKIN, COMBUST. MORPHOLINE -CORR TO EYES/SKIN.
DIETHYLAMINOETHANOL-CORR TO EYES, SKIN IRRIT. CYCLO.=TWA 10 PPM, 41
MG/M3 ACGIH/TLV. MORPHOLINE=TWA 20 PPM, 71 MG/M3 ACGIH/TLV.
DIETHYL.=TWA 10 PPM, 48 MG/M3 (SKIN) ACGIH/TLV. CYCL O.=TWA 10 PPM,
40 MG/M3 OSHA/PEL 70 MG/M3, 105 MG/M3 OSHA/PEL. DIETHYL.=TWA 10
PPM, 50 MG/M3 (SKIN) OSHA/PEL. (CONTACT NEHC FOR ADDITIONAL
INFORMATION).
State Regulatory Information:CA PROP 65-PROD CONTAINS NO CHEMS WHICH
REQUIRE WARNING UNDER PROP 65. MICHIGAN CRITICAL MATLS-PROD DOES
NOT CONTAIN INGRED LISTED ON MI CRITICAL MATLS REG. STATE
RIGHT-TO-KNOW LAWS: FOLLOWING INGRED ARE DISCLOSED FOR
COMPLIANCE-CYCLOHEXYLAMINE: 108-91-8. DIETHYLAMINOETHANOL:
100-37-8. MORPHOLINE: 110-91-8. WATER: 7732-18-5. INTERNAT'L
REGS-THIS IS A WHMIS-CONTROLLED PROD UNDER HOUSE OF COMMONS (C
ANADA) BILL C-70 (CLASS E). PROD CONTAINS SUBST(S), (LISTED ABOVE,
EXCEPT WATER) FROM INGRED DISCLOS URE LIST OR HAS BEEN EVALUATED
BASED ON ITS TOX PROPERTIES, TO CONTAIN THOSE HAZ INGREDIENTS(S).
(CONTACT NEHC FOR ADDITIONAL INFORMATION).